Polymer geometry and Li+ conduction in poly(ethylene oxide)

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Polymer geometry and Li+ conduction in poly(ethylene oxide)

We study the effect of molecular shape on Li+ conduction in dilute and concentrated polymer electrolytes (LiI : P (EO)n(3 ≤ n ≤ 100)). We model the migration-diffusion of interacting Li+ ions in the helical PEO molecule as Brownian motion in a field of electrical force. Our model demonstrates that ionic conductivity of the amorphous PE structure is increased by mechanical stretching due to the ...

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ژورنال

عنوان ژورنال: Journal of Computational Physics

سال: 2008

ISSN: 0021-9991

DOI: 10.1016/j.jcp.2008.06.006